Synthesis and characterization of advanced carbon nano-forms with polymers
Abstract
The polymer – carbon nanoforms (CNFs) composites generally are separated in two categories the blends in which the polymeric matrix and the CNFs filler are not bonded chemically and the composites where there is a chemical bond between polymeric matrix and CNFs filler. These chemically bonded composites are synthesized via the “grafting to” and the “grafting from” methods. In the former, the polymer is synthesized with standard polymerization techniques (anionic, cationic, atom transfer radical polymerization etc.) and then the “living” polymer reacts with the CNTs to form chemical bond, whereas in the later the polymerization procedure starts from the CNTs after proper treatment resulting in a polymer with no controlled final molecular weight or polydispersity index.In this work, we have studied the synthesis of polymer-MWCNTs and polymer-CMGs (chemically modified graphene oxide) composites chemically bonded via the “grafting to” method in order to have better control of the polymer m ...
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